Browsing through my Facebook statuses, I saw a post by Transparent Spanish with a link to a Pocoyó episode with subtitles in English and Spanish.
Personally, I think I would rather have it with just Spanish subtitles or no subtitles, but for beginners, I think these videos would be helpful. After watching them a few times, you then could search for the episodes without any subtitles and see how much you understand.
Where to go:     
YouTube channel with subtitled Pocoyó episodes     
Transparent Spanish Facebook Page     
Official Pocoyó Page

 
 

